Abstract

Strong Coulomb interactions can drive electrons to crystallize into a Wigner lattice. Achieving the bosonic analogue – a crystal of excitons – has remained elusive due to their short lifetimes and weaker interactions. Here, we report the observation of a thermodynamically stable exciton crystal in an excitonic insulator coupled to a moiré potential. Using an electron-hole bilayer composed of a monolayer MoSe₂ and a WS₂/WSe₂ moiré superlattice, we construct a tunable extended Bose-Hubbard model with electrical control over exciton and charge doping in thermal equilibrium. Optical spectroscopy reveals spontaneous crystallization of long-lived excitons at one exciton filling per three moiré sites, evidenced by strong Umklapp scattering peaks in the optical spectrum. Exciton transport measurements further show a pronounced exciton resistance peak at the same filling, consistent with suppressed exciton hopping in a crystalline phase. When doped away from net charge neutrality, this moiré electron-hole bilayer can host new correlated insulating phases where dipolar excitonic insulators form on top of the background of a hole Mott insulator or generalized Wigner crystals in the moiré superlattice. These findings establish moiré excitonic insulators as a versatile platform for realizing correlated crystalline phases of bosons and fermions.

Abstract

Strong Coulomb interactions can drive electrons to crystallize into a Wigner lattice. Achieving the bosonic analogue – a crystal of excitons – has remained elusive due to their short lifetimes and weaker interactions. Here, we report the observation of a thermodynamically stable exciton crystal in an excitonic insulator coupled to a moiré potential. Using an electron-hole bilayer composed of a monolayer MoSe₂ and a WS₂/WSe₂ moiré superlattice, we construct a tunable extended Bose-Hubbard model with electrical control over exciton and charge doping in thermal equilibrium. Optical spectroscopy reveals spontaneous crystallization of long-lived excitons at one exciton filling per three moiré sites, evidenced by strong Umklapp scattering peaks in the optical spectrum. Exciton transport measurements further show a pronounced exciton resistance peak at the same filling, consistent with suppressed exciton hopping in a crystalline phase. When doped away from net charge neutrality, this moiré electron-hole bilayer can host new correlated insulating phases where dipolar excitonic insulators form on top of the background of a hole Mott insulator or generalized Wigner crystals in the moiré superlattice. These findings establish moiré excitonic insulators as a versatile platform for realizing correlated crystalline phases of bosons and fermions.

Abstract

Strong Coulomb interactions can drive electrons to crystallize into a Wigner lattice. Achieving the bosonic analogue – a crystal of excitons – has remained elusive due to their short lifetimes and weaker interactions. Here, we report the observation of a thermodynamically stable exciton crystal in an excitonic insulator coupled to a moiré potential. Using an electron-hole bilayer composed of a monolayer MoSe₂ and a WS₂/WSe₂ moiré superlattice, we construct a tunable extended Bose-Hubbard model with electrical control over exciton and charge doping in thermal equilibrium. Optical spectroscopy reveals spontaneous crystallization of long-lived excitons at one exciton filling per three moiré sites, evidenced by strong Umklapp scattering peaks in the optical spectrum. Exciton transport measurements further show a pronounced exciton resistance peak at the same filling, consistent with suppressed exciton hopping in a crystalline phase. When doped away from net charge neutrality, this moiré electron-hole bilayer can host new correlated insulating phases where dipolar excitonic insulators form on top of the background of a hole Mott insulator or generalized Wigner crystals in the moiré superlattice. These findings establish moiré excitonic insulators as a versatile platform for realizing correlated crystalline phases of bosons and fermions.

Abstract

Strong Coulomb interactions can drive electrons to crystallize into a Wigner lattice. Achieving the bosonic analogue – a crystal of excitons – has remained elusive due to their short lifetimes and weaker interactions. Here, we report the observation of a thermodynamically stable exciton crystal in an excitonic insulator coupled to a moiré potential. Using an electron-hole bilayer composed of a monolayer MoSe₂ and a WS₂/WSe₂ moiré superlattice, we construct a tunable extended Bose-Hubbard model with electrical control over exciton and charge doping in thermal equilibrium. Optical spectroscopy reveals spontaneous crystallization of long-lived excitons at one exciton filling per three moiré sites, evidenced by strong Umklapp scattering peaks in the optical spectrum. Exciton transport measurements further show a pronounced exciton resistance peak at the same filling, consistent with suppressed exciton hopping in a crystalline phase. When doped away from net charge neutrality, this moiré electron-hole bilayer can host new correlated insulating phases where dipolar excitonic insulators form on top of the background of a hole Mott insulator or generalized Wigner crystals in the moiré superlattice. These findings establish moiré excitonic insulators as a versatile platform for realizing correlated crystalline phases of bosons and fermions.