Encapsulation of the Graphene Nanoribbon Precursor 1,2,4-trichlorobenzene in Boron Nitride Nanotubes at Room Temperature

Ana Cadena; Áron Pekker; Bea Botka; Erzsébet Dodony; Zsolt Fogarassy; Béla Pécz; Katalin Kamarás

doi:10.1002/pssr.202200284

Paper details

Research paper

Experimental GrowthExperimental Characterization

Encapsulation of the Graphene Nanoribbon Precursor 1,2,4-trichlorobenzene in Boron Nitride Nanotubes at Room Temperature

Ana Cadena, Áron Pekker, Bea Botka, Erzsébet Dodony et al.

arXiv preprint·2022·10.1002/pssr.202200284·arXiv:2208.02081

Samples

Each sample groups how it was prepared, characterized, and measured. Click a card to expand.

As-received boron nitride nanotube sample before filling.

2 characterizations1 property2 figures

ExperimentalBNStudied Material

BNNT sample after room-temperature liquid-phase encapsulation with 1,2,4-trichlorobenzene.

1 preparation3 characterizations5 properties2 figures

ExperimentalBNStudied MaterialC₆H₃Cl₃Precursor

Encapsulated sample after annealing at 500 °C, showing partial conversion toward graphene nanoribbons.

1 preparation3 characterizations5 properties2 figures

ExperimentalBNStudied MaterialC₆H₃Cl₃PrecursorCStudied Material

Annealed sample at 700 °C with graphene nanoribbon-like carbon structures inside BNNTs.

1 preparation5 characterizations7 properties5 figures

ExperimentalBNStudied MaterialCStudied Material

Materials

boron nitride nanotube

Studied Material

Also known as

BNNTboron nitride nanotubes

studied material

1,2,4-trichlorobenzene

C₆H₃Cl₃

Precursor

Why these are connected

Related documents with shared materials, methods, properties, or citations.

Encapsulation of the Graphene Nanoribbon Precursor 1,2,4-trichlorobenzene in Boron Nitride Nanotubes at Room Temperature | Matter42 Literature

Properties

Type	Label	Value	Material	Sample	Condition	Source
Raman Peak	E2g	1358cm⁻¹	BN	As-received boron nitride nanotube sample before filling.BNNT sample after room-temperature liquid-phase encapsulatio Encapsulated sample after annealing at 500 °C, showing parti Annealed sample at 700 °C with graphene nanoribbon-like carb		—
Raman Peak	G	1598cm⁻¹	C	BNNT sample after room-temperature liquid-phase encapsulatio Encapsulated sample after annealing at 500 °C, showing parti Annealed sample at 700 °C with graphene nanoribbon-like carb		—
Raman Peak	C-H in-plane bending	1223cm⁻¹	C	Annealed sample at 700 °C with graphene nanoribbon-like carb		—
Ir Band Position	encapsulated TCB vibrational band	1027cm⁻¹	C₆H₃Cl₃	BNNT sample after room-temperature liquid-phase encapsulatio Encapsulated sample after annealing at 500 °C, showing parti		—
Ir Band Position	encapsulated TCB vibrational band	1105cm⁻¹	C₆H₃Cl₃	BNNT sample after room-temperature liquid-phase encapsulatio Encapsulated sample after annealing at 500 °C, showing parti		—
Ir Band Position	encapsulated TCB vibrational band	1192cm⁻¹	C₆H₃Cl₃	BNNT sample after room-temperature liquid-phase encapsulatio Encapsulated sample after annealing at 500 °C, showing parti		—
Nanotube Inner Diameter	mean inner diameter	2.35nm	BN	Annealed sample at 700 °C with graphene nanoribbon-like carb		—
Nanotube Inner Diameter Std	standard deviation of inner diameter	0.96nm	BN	Annealed sample at 700 °C with graphene nanoribbon-like carb		—
Nanoribbon Width Range	estimated width range	0.5-1.8nm	C	Annealed sample at 700 °C with graphene nanoribbon-like carb		—
Nanoribbon Size Class	supported ribbon families	3<N<14 AGNR and 2<N<8 ZGNR	C	Annealed sample at 700 °C with graphene nanoribbon-like carb		—
Optical Band Gap	band gap	5.7eV	—	—	—	—

Properties

Type	Label	Value	Material	Sample	Condition	Source
Raman Peak	E2g	1358cm⁻¹	BN	As-received boron nitride nanotube sample before filling.BNNT sample after room-temperature liquid-phase encapsulatio Encapsulated sample after annealing at 500 °C, showing parti Annealed sample at 700 °C with graphene nanoribbon-like carb		—
Raman Peak	G	1598cm⁻¹	C	BNNT sample after room-temperature liquid-phase encapsulatio Encapsulated sample after annealing at 500 °C, showing parti Annealed sample at 700 °C with graphene nanoribbon-like carb		—
Raman Peak	C-H in-plane bending	1223cm⁻¹	C	Annealed sample at 700 °C with graphene nanoribbon-like carb		—
Ir Band Position	encapsulated TCB vibrational band	1027cm⁻¹	C₆H₃Cl₃	BNNT sample after room-temperature liquid-phase encapsulatio Encapsulated sample after annealing at 500 °C, showing parti		—
Ir Band Position	encapsulated TCB vibrational band	1105cm⁻¹	C₆H₃Cl₃	BNNT sample after room-temperature liquid-phase encapsulatio Encapsulated sample after annealing at 500 °C, showing parti		—
Ir Band Position	encapsulated TCB vibrational band	1192cm⁻¹	C₆H₃Cl₃	BNNT sample after room-temperature liquid-phase encapsulatio Encapsulated sample after annealing at 500 °C, showing parti		—
Nanotube Inner Diameter	mean inner diameter	2.35nm	BN	Annealed sample at 700 °C with graphene nanoribbon-like carb		—
Nanotube Inner Diameter Std	standard deviation of inner diameter	0.96nm	BN	Annealed sample at 700 °C with graphene nanoribbon-like carb		—
Nanoribbon Width Range	estimated width range	0.5-1.8nm	C	Annealed sample at 700 °C with graphene nanoribbon-like carb		—
Nanoribbon Size Class	supported ribbon families	3<N<14 AGNR and 2<N<8 ZGNR	C	Annealed sample at 700 °C with graphene nanoribbon-like carb		—
Optical Band Gap	band gap	5.7eV	—	—	—	—

Properties

Type	Label	Value	Material	Sample	Condition	Source
Raman Peak	E2g	1358cm⁻¹	BN	As-received boron nitride nanotube sample before filling.BNNT sample after room-temperature liquid-phase encapsulatio Encapsulated sample after annealing at 500 °C, showing parti Annealed sample at 700 °C with graphene nanoribbon-like carb		—
Raman Peak	G	1598cm⁻¹	C	BNNT sample after room-temperature liquid-phase encapsulatio Encapsulated sample after annealing at 500 °C, showing parti Annealed sample at 700 °C with graphene nanoribbon-like carb		—
Raman Peak	C-H in-plane bending	1223cm⁻¹	C	Annealed sample at 700 °C with graphene nanoribbon-like carb		—
Ir Band Position	encapsulated TCB vibrational band	1027cm⁻¹	C₆H₃Cl₃	BNNT sample after room-temperature liquid-phase encapsulatio Encapsulated sample after annealing at 500 °C, showing parti		—
Ir Band Position	encapsulated TCB vibrational band	1105cm⁻¹	C₆H₃Cl₃	BNNT sample after room-temperature liquid-phase encapsulatio Encapsulated sample after annealing at 500 °C, showing parti		—
Ir Band Position	encapsulated TCB vibrational band	1192cm⁻¹	C₆H₃Cl₃	BNNT sample after room-temperature liquid-phase encapsulatio Encapsulated sample after annealing at 500 °C, showing parti		—
Nanotube Inner Diameter	mean inner diameter	2.35nm	BN	Annealed sample at 700 °C with graphene nanoribbon-like carb		—
Nanotube Inner Diameter Std	standard deviation of inner diameter	0.96nm	BN	Annealed sample at 700 °C with graphene nanoribbon-like carb		—
Nanoribbon Width Range	estimated width range	0.5-1.8nm	C	Annealed sample at 700 °C with graphene nanoribbon-like carb		—
Nanoribbon Size Class	supported ribbon families	3<N<14 AGNR and 2<N<8 ZGNR	C	Annealed sample at 700 °C with graphene nanoribbon-like carb		—
Optical Band Gap	band gap	5.7eV	—	—	—	—

Properties

Type	Label	Value	Material	Sample	Condition	Source
Raman Peak	E2g	1358cm⁻¹	BN	As-received boron nitride nanotube sample before filling.BNNT sample after room-temperature liquid-phase encapsulatio Encapsulated sample after annealing at 500 °C, showing parti Annealed sample at 700 °C with graphene nanoribbon-like carb		—
Raman Peak	G	1598cm⁻¹	C	BNNT sample after room-temperature liquid-phase encapsulatio Encapsulated sample after annealing at 500 °C, showing parti Annealed sample at 700 °C with graphene nanoribbon-like carb		—
Raman Peak	C-H in-plane bending	1223cm⁻¹	C	Annealed sample at 700 °C with graphene nanoribbon-like carb		—
Ir Band Position	encapsulated TCB vibrational band	1027cm⁻¹	C₆H₃Cl₃	BNNT sample after room-temperature liquid-phase encapsulatio Encapsulated sample after annealing at 500 °C, showing parti		—
Ir Band Position	encapsulated TCB vibrational band	1105cm⁻¹	C₆H₃Cl₃	BNNT sample after room-temperature liquid-phase encapsulatio Encapsulated sample after annealing at 500 °C, showing parti		—
Ir Band Position	encapsulated TCB vibrational band	1192cm⁻¹	C₆H₃Cl₃	BNNT sample after room-temperature liquid-phase encapsulatio Encapsulated sample after annealing at 500 °C, showing parti		—
Nanotube Inner Diameter	mean inner diameter	2.35nm	BN	Annealed sample at 700 °C with graphene nanoribbon-like carb		—
Nanotube Inner Diameter Std	standard deviation of inner diameter	0.96nm	BN	Annealed sample at 700 °C with graphene nanoribbon-like carb		—
Nanoribbon Width Range	estimated width range	0.5-1.8nm	C	Annealed sample at 700 °C with graphene nanoribbon-like carb		—
Nanoribbon Size Class	supported ribbon families	3<N<14 AGNR and 2<N<8 ZGNR	C	Annealed sample at 700 °C with graphene nanoribbon-like carb		—
Optical Band Gap	band gap	5.7eV	—	—	—	—