Patent
US 10,808,1421,3,6-trinitropyrene
1,2-dinitropyrene
1,6-dinitropyrene
1,3,6-trichloropyrene
1,3,6,8-tetrachloropyrene
catalyst
composition solvent
FIGS. 6A to 6 C illustrate results of X-ray photoelectron spectroscopy on graphene quantum dots prepared in Preparation Example 2 and Comparative Preparation …
FIG. 7B illustrates results of Raman spectroscopy on graphene quantum dots prepared in Comparative Preparation Example 1 and 1,3,6-trinitropyrene (TNP); [25]
NMR no peak at 9-10 ppm chemical shift |
| — |
graphene quantum dot |
XPS C1s peak binding energy of hardmask product | — | graphene quantum dot |
XPS sp3 C-N peak binding energy of hardmask product | — | graphene quantum dot |
XPS O1s peak binding energy of hardmask product | — | graphene quantum dot |
XPS N1s peak binding energy of hardmask product | — | graphene quantum dot |
C:N atom ratio in graphene quantum dot | — | graphene quantum dot |
Thickness | 0.1–10 nm | — |
— | 284–290 eV | — |
— | 287–289 eV | — |
— | 530–535 eV | — |
— | 398–402 eV | — |
Thickness | 1–50 nm | — |
Thickness | 1–30 nm | — |
Thickness | 1–10 nm | — |
Thickness | 2–10 nm | — |
Thickness | 5–8 nm | — |
Thickness | 6–8 nm | — |
Thickness | 0.5–5 nm | — |
Thickness | 0.01–10 nm | — |
Thickness | 0.34–100 nm | — |
Thickness | 0.334–0.478 nm | — |
Thickness | 0.6–2 nm | — |
Thickness | 0.7–1 nm | — |
Thickness | 0.3–0.7 nm | — |
Thickness | 10–10000 nm | — |
Thickness | 10–1000 nm | — |
Thickness | 100–500 nm | — |
Thickness | 1–1350 cm | — |
Thickness | 1–3700 cm | — |
Thickness | 1–1800 cm | — |
Thickness | 1340–1350 cm | — |
1,3,6-trinitropyrene
1,2-dinitropyrene
1,6-dinitropyrene
1,3,6-trichloropyrene
1,3,6,8-tetrachloropyrene
catalyst
composition solvent
FIGS. 6A to 6 C illustrate results of X-ray photoelectron spectroscopy on graphene quantum dots prepared in Preparation Example 2 and Comparative Preparation …
FIG. 7B illustrates results of Raman spectroscopy on graphene quantum dots prepared in Comparative Preparation Example 1 and 1,3,6-trinitropyrene (TNP); [25]
NMR no peak at 9-10 ppm chemical shift |
| — |
graphene quantum dot |
XPS C1s peak binding energy of hardmask product | — | graphene quantum dot |
XPS sp3 C-N peak binding energy of hardmask product | — | graphene quantum dot |
XPS O1s peak binding energy of hardmask product | — | graphene quantum dot |
XPS N1s peak binding energy of hardmask product | — | graphene quantum dot |
C:N atom ratio in graphene quantum dot | — | graphene quantum dot |
Thickness | 0.1–10 nm | — |
— | 284–290 eV | — |
— | 287–289 eV | — |
— | 530–535 eV | — |
— | 398–402 eV | — |
Thickness | 1–50 nm | — |
Thickness | 1–30 nm | — |
Thickness | 1–10 nm | — |
Thickness | 2–10 nm | — |
Thickness | 5–8 nm | — |
Thickness | 6–8 nm | — |
Thickness | 0.5–5 nm | — |
Thickness | 0.01–10 nm | — |
Thickness | 0.34–100 nm | — |
Thickness | 0.334–0.478 nm | — |
Thickness | 0.6–2 nm | — |
Thickness | 0.7–1 nm | — |
Thickness | 0.3–0.7 nm | — |
Thickness | 10–10000 nm | — |
Thickness | 10–1000 nm | — |
Thickness | 100–500 nm | — |
Thickness | 1–1350 cm | — |
Thickness | 1–3700 cm | — |
Thickness | 1–1800 cm | — |
Thickness | 1340–1350 cm | — |
1,3,6-trinitropyrene
1,2-dinitropyrene
1,6-dinitropyrene
1,3,6-trichloropyrene
1,3,6,8-tetrachloropyrene
catalyst
composition solvent
FIGS. 6A to 6 C illustrate results of X-ray photoelectron spectroscopy on graphene quantum dots prepared in Preparation Example 2 and Comparative Preparation …
FIG. 7B illustrates results of Raman spectroscopy on graphene quantum dots prepared in Comparative Preparation Example 1 and 1,3,6-trinitropyrene (TNP); [25]
NMR no peak at 9-10 ppm chemical shift |
| — |
graphene quantum dot |
XPS C1s peak binding energy of hardmask product | — | graphene quantum dot |
XPS sp3 C-N peak binding energy of hardmask product | — | graphene quantum dot |
XPS O1s peak binding energy of hardmask product | — | graphene quantum dot |
XPS N1s peak binding energy of hardmask product | — | graphene quantum dot |
C:N atom ratio in graphene quantum dot | — | graphene quantum dot |
Thickness | 0.1–10 nm | — |
— | 284–290 eV | — |
— | 287–289 eV | — |
— | 530–535 eV | — |
— | 398–402 eV | — |
Thickness | 1–50 nm | — |
Thickness | 1–30 nm | — |
Thickness | 1–10 nm | — |
Thickness | 2–10 nm | — |
Thickness | 5–8 nm | — |
Thickness | 6–8 nm | — |
Thickness | 0.5–5 nm | — |
Thickness | 0.01–10 nm | — |
Thickness | 0.34–100 nm | — |
Thickness | 0.334–0.478 nm | — |
Thickness | 0.6–2 nm | — |
Thickness | 0.7–1 nm | — |
Thickness | 0.3–0.7 nm | — |
Thickness | 10–10000 nm | — |
Thickness | 10–1000 nm | — |
Thickness | 100–500 nm | — |
Thickness | 1–1350 cm | — |
Thickness | 1–3700 cm | — |
Thickness | 1–1800 cm | — |
Thickness | 1340–1350 cm | — |
1,3,6-trinitropyrene
1,2-dinitropyrene
1,6-dinitropyrene
1,3,6-trichloropyrene
1,3,6,8-tetrachloropyrene
catalyst
composition solvent
FIGS. 6A to 6 C illustrate results of X-ray photoelectron spectroscopy on graphene quantum dots prepared in Preparation Example 2 and Comparative Preparation …
FIG. 7B illustrates results of Raman spectroscopy on graphene quantum dots prepared in Comparative Preparation Example 1 and 1,3,6-trinitropyrene (TNP); [25]
NMR no peak at 9-10 ppm chemical shift |
| — |
graphene quantum dot |
XPS C1s peak binding energy of hardmask product | — | graphene quantum dot |
XPS sp3 C-N peak binding energy of hardmask product | — | graphene quantum dot |
XPS O1s peak binding energy of hardmask product | — | graphene quantum dot |
XPS N1s peak binding energy of hardmask product | — | graphene quantum dot |
C:N atom ratio in graphene quantum dot | — | graphene quantum dot |
Thickness | 0.1–10 nm | — |
— | 284–290 eV | — |
— | 287–289 eV | — |
— | 530–535 eV | — |
— | 398–402 eV | — |
Thickness | 1–50 nm | — |
Thickness | 1–30 nm | — |
Thickness | 1–10 nm | — |
Thickness | 2–10 nm | — |
Thickness | 5–8 nm | — |
Thickness | 6–8 nm | — |
Thickness | 0.5–5 nm | — |
Thickness | 0.01–10 nm | — |
Thickness | 0.34–100 nm | — |
Thickness | 0.334–0.478 nm | — |
Thickness | 0.6–2 nm | — |
Thickness | 0.7–1 nm | — |
Thickness | 0.3–0.7 nm | — |
Thickness | 10–10000 nm | — |
Thickness | 10–1000 nm | — |
Thickness | 100–500 nm | — |
Thickness | 1–1350 cm | — |
Thickness | 1–3700 cm | — |
Thickness | 1–1800 cm | — |
Thickness | 1340–1350 cm | — |