GALLIUM NITRIDE SUBSTRATE AND MANUFACTURING METHOD OF NITRIDE SEMICONDUCTOR CRYSTAL | Matter42 Literature
Patent
Atlas literature
Patent
US 11,670,687 B2
GALLIUM NITRIDE SUBSTRATE AND MANUFACTURING METHOD OF NITRIDE SEMICONDUCTOR CRYSTAL
Yusuke Tsukada, Shuichi Kubo, Kazunori Kamada, Hideo Fujisawa et al.
MITSUBISHI CHEMICAL CORPORATION, Tokyo (JP)·Jun. 6, 2023·US
Drawings
Patent drawings and their descriptions. Click a drawing to enlarge it.
FIG. 1
FIGS. 1A and 1B, the substrate 1 has two main surfaces 11 parallel to each other and an edge surface 12. Chamfering can be performed, as necessary, for …
FIG. 2
FIG. 2. The crystal growth apparatus 2 depicted in
FIG. 3
FIG. 3. In the crystal growth apparatus 3 depicted in
FIG. 4
FIG. 4, a plate-like GaN crystal of which thickness direction is the m-axis direction is grown from the opening of the mask pattern. The secondary substrate …
FIG. 5
FIG. 5, the heating rate is constant from the heating step to the initial growth step. In the example of
FIG. 6
FIG. 6, between the heating step and the initial growth step, the temperature keeping step of keeping the substrate tem- perature constant is provided. The …
FIG. 7
FIG. 7, the heating rate is changed at the early and later stages of the initial growth step. In this example, the heating rate is changed discontinuously, but …
FIG. 8
FIG. 8 is a cross-sectional view, and the semiconductor light- emitting device 40A has a semiconductor laminate L grown 65 on the main surface of the GaN …
FIG. 9
FIG. 9 having a negative electrode 46 on the backside of the GaN substrate 41, the lowering effect of the operating voltage due to the increased carrier …
FIG. 10
FIG. 10 is a schematic diagram for explaining a structure of a GaN layer bonded substrate.
FIG. 11
FIG. 11 is a cross-sectional view depicting two seed substrates arranged on a susceptor. MODE FOR CARRYING OUT THE INVENTION The surface of a nitride …
Claims
Claims define the patent's legal scope. Independent claims stand alone; dependent claims (nested) narrow them. Click a claim to expand its dependents.
1 independent · 14 dependent
1
IndependentGaNnon-polar or semi-polar GaN substrate
A gallium nitride substrate comprising a first main surface and a second main surface opposite thereto, wherein the first main surface is a non-polar or semi-polar plane, a dislocation density measured by a room-temperature cathode luminescence method averaged over a whole of the first main surface is 1×104 cm⁻² or less, and an averaged dislocation density measured by a room-temperature cathode luminescence method in an arbi-trary selected square region sizing 250 µm×250 µm in the first main surface is 1×106 cm⁻² or less.
2
Dependent← claim 1GaNnon-polar or semi-polar GaN substrate
A gallium nitride substrate according to claim 1, wherein the dislocation density is 10 cm⁻² or less.
3
Dependent← claim 1GaNnon-polar or semi-polar GaN substrate
A gallium nitride substrate according to claim 1, wherein the averaged dislocation density is 1×104 cm⁻² or less.
4
Dependent← claim 1GaNnon-polar or semi-polar GaN substrate
A gallium nitride substrate according to claim 1, wherein an area of the first main surface is 1.0 cm2 or more.
5
Dependent← claim 1GaNnon-polar or semi-polar GaN substrate
A gallium nitride substrate according to claim 1, wherein a stacking fault density in the first main surface is 10 cm⁻¹ or less.
6
Dependent← claim 1GaNnon-polar or semi-polar GaN substrate
A gallium nitride substrate according to claim 1, wherein the first main surface is an M-plane.
7
Dependent← claim 1GaNnon-polar or semi-polar GaN substrate
A gallium nitride substrate according to claim 1, wherein the first main surface has a normal vector of which is tilted from <10-10> direction to c-axis direc-tion, and the normal vector is between <10-11> direction and <10-1-1> direction.
A method for manufacturing a nitride semiconductor crystal, comprising: growing a nitride semiconductor crystal on the first main surface of the gallium nitride substrate according to claim 1.
Device structures
Layer stacks claimed or described, ordered top of device to substrate.
non-polar or semi-polar GaN substrate
GaNsubstrate
semiconductor light-emitting device
GaNp-type layer
nitride semiconductor crystallight-emitting layer
GaNn-type layer
GaNsubstrate
Materials
Materials described outside the worked examples.
gallium nitride (GaN) substrate
GaN
Substrate
Epitaxial LayerBulk Crystal Source
nitride semiconductor crystal
Process steps
Additional fabrication and treatment steps described in the patent.
1
Hvpe Growth
Step 1
Process details
notes:Used to grow bulk GaN crystal for subsequent slicing into non-polar or semi-polar substrates
method:HVPE (Hydride Vapor Phase Epitaxy)
product:bulk GaN crystal
Materials:GaN
Characterization
Measurements and analyses referenced in the patent, with their drawing references.
thickness
Thickness
FIG. 4, a plate-like GaN crystal of which thickness direction is the m-axis direction is grown from the opening of the mask pattern. The secondary substrate …
GALLIUM NITRIDE SUBSTRATE AND MANUFACTURING METHOD OF NITRIDE SEMICONDUCTOR CRYSTAL
Yusuke Tsukada, Shuichi Kubo, Kazunori Kamada, Hideo Fujisawa et al.
MITSUBISHI CHEMICAL CORPORATION, Tokyo (JP)·Jun. 6, 2023·US
Drawings
Patent drawings and their descriptions. Click a drawing to enlarge it.
FIG. 1
FIGS. 1A and 1B, the substrate 1 has two main surfaces 11 parallel to each other and an edge surface 12. Chamfering can be performed, as necessary, for …
FIG. 2
FIG. 2. The crystal growth apparatus 2 depicted in
FIG. 3
FIG. 3. In the crystal growth apparatus 3 depicted in
FIG. 4
FIG. 4, a plate-like GaN crystal of which thickness direction is the m-axis direction is grown from the opening of the mask pattern. The secondary substrate …
FIG. 5
FIG. 5, the heating rate is constant from the heating step to the initial growth step. In the example of
FIG. 6
FIG. 6, between the heating step and the initial growth step, the temperature keeping step of keeping the substrate tem- perature constant is provided. The …
FIG. 7
FIG. 7, the heating rate is changed at the early and later stages of the initial growth step. In this example, the heating rate is changed discontinuously, but …
FIG. 8
FIG. 8 is a cross-sectional view, and the semiconductor light- emitting device 40A has a semiconductor laminate L grown 65 on the main surface of the GaN …
FIG. 9
FIG. 9 having a negative electrode 46 on the backside of the GaN substrate 41, the lowering effect of the operating voltage due to the increased carrier …
FIG. 10
FIG. 10 is a schematic diagram for explaining a structure of a GaN layer bonded substrate.
FIG. 11
FIG. 11 is a cross-sectional view depicting two seed substrates arranged on a susceptor. MODE FOR CARRYING OUT THE INVENTION The surface of a nitride …
Claims
Claims define the patent's legal scope. Independent claims stand alone; dependent claims (nested) narrow them. Click a claim to expand its dependents.
1 independent · 14 dependent
1
IndependentGaNnon-polar or semi-polar GaN substrate
A gallium nitride substrate comprising a first main surface and a second main surface opposite thereto, wherein the first main surface is a non-polar or semi-polar plane, a dislocation density measured by a room-temperature cathode luminescence method averaged over a whole of the first main surface is 1×104 cm⁻² or less, and an averaged dislocation density measured by a room-temperature cathode luminescence method in an arbi-trary selected square region sizing 250 µm×250 µm in the first main surface is 1×106 cm⁻² or less.
2
Dependent← claim 1GaNnon-polar or semi-polar GaN substrate
A gallium nitride substrate according to claim 1, wherein the dislocation density is 10 cm⁻² or less.
3
Dependent← claim 1GaNnon-polar or semi-polar GaN substrate
A gallium nitride substrate according to claim 1, wherein the averaged dislocation density is 1×104 cm⁻² or less.
4
Dependent← claim 1GaNnon-polar or semi-polar GaN substrate
A gallium nitride substrate according to claim 1, wherein an area of the first main surface is 1.0 cm2 or more.
5
Dependent← claim 1GaNnon-polar or semi-polar GaN substrate
A gallium nitride substrate according to claim 1, wherein a stacking fault density in the first main surface is 10 cm⁻¹ or less.
6
Dependent← claim 1GaNnon-polar or semi-polar GaN substrate
A gallium nitride substrate according to claim 1, wherein the first main surface is an M-plane.
7
Dependent← claim 1GaNnon-polar or semi-polar GaN substrate
A gallium nitride substrate according to claim 1, wherein the first main surface has a normal vector of which is tilted from <10-10> direction to c-axis direc-tion, and the normal vector is between <10-11> direction and <10-1-1> direction.
A method for manufacturing a nitride semiconductor crystal, comprising: growing a nitride semiconductor crystal on the first main surface of the gallium nitride substrate according to claim 1.
Device structures
Layer stacks claimed or described, ordered top of device to substrate.
non-polar or semi-polar GaN substrate
GaNsubstrate
semiconductor light-emitting device
GaNp-type layer
nitride semiconductor crystallight-emitting layer
GaNn-type layer
GaNsubstrate
Materials
Materials described outside the worked examples.
gallium nitride (GaN) substrate
GaN
Substrate
Epitaxial LayerBulk Crystal Source
nitride semiconductor crystal
Process steps
Additional fabrication and treatment steps described in the patent.
1
Hvpe Growth
Step 1
Process details
notes:Used to grow bulk GaN crystal for subsequent slicing into non-polar or semi-polar substrates
method:HVPE (Hydride Vapor Phase Epitaxy)
product:bulk GaN crystal
Materials:GaN
Characterization
Measurements and analyses referenced in the patent, with their drawing references.
thickness
Thickness
FIG. 4, a plate-like GaN crystal of which thickness direction is the m-axis direction is grown from the opening of the mask pattern. The secondary substrate …
GALLIUM NITRIDE SUBSTRATE AND MANUFACTURING METHOD OF NITRIDE SEMICONDUCTOR CRYSTAL
Yusuke Tsukada, Shuichi Kubo, Kazunori Kamada, Hideo Fujisawa et al.
MITSUBISHI CHEMICAL CORPORATION, Tokyo (JP)·Jun. 6, 2023·US
Drawings
Patent drawings and their descriptions. Click a drawing to enlarge it.
FIG. 1
FIGS. 1A and 1B, the substrate 1 has two main surfaces 11 parallel to each other and an edge surface 12. Chamfering can be performed, as necessary, for …
FIG. 2
FIG. 2. The crystal growth apparatus 2 depicted in
FIG. 3
FIG. 3. In the crystal growth apparatus 3 depicted in
FIG. 4
FIG. 4, a plate-like GaN crystal of which thickness direction is the m-axis direction is grown from the opening of the mask pattern. The secondary substrate …
FIG. 5
FIG. 5, the heating rate is constant from the heating step to the initial growth step. In the example of
FIG. 6
FIG. 6, between the heating step and the initial growth step, the temperature keeping step of keeping the substrate tem- perature constant is provided. The …
FIG. 7
FIG. 7, the heating rate is changed at the early and later stages of the initial growth step. In this example, the heating rate is changed discontinuously, but …
FIG. 8
FIG. 8 is a cross-sectional view, and the semiconductor light- emitting device 40A has a semiconductor laminate L grown 65 on the main surface of the GaN …
FIG. 9
FIG. 9 having a negative electrode 46 on the backside of the GaN substrate 41, the lowering effect of the operating voltage due to the increased carrier …
FIG. 10
FIG. 10 is a schematic diagram for explaining a structure of a GaN layer bonded substrate.
FIG. 11
FIG. 11 is a cross-sectional view depicting two seed substrates arranged on a susceptor. MODE FOR CARRYING OUT THE INVENTION The surface of a nitride …
Claims
Claims define the patent's legal scope. Independent claims stand alone; dependent claims (nested) narrow them. Click a claim to expand its dependents.
1 independent · 14 dependent
1
IndependentGaNnon-polar or semi-polar GaN substrate
A gallium nitride substrate comprising a first main surface and a second main surface opposite thereto, wherein the first main surface is a non-polar or semi-polar plane, a dislocation density measured by a room-temperature cathode luminescence method averaged over a whole of the first main surface is 1×104 cm⁻² or less, and an averaged dislocation density measured by a room-temperature cathode luminescence method in an arbi-trary selected square region sizing 250 µm×250 µm in the first main surface is 1×106 cm⁻² or less.
2
Dependent← claim 1GaNnon-polar or semi-polar GaN substrate
A gallium nitride substrate according to claim 1, wherein the dislocation density is 10 cm⁻² or less.
3
Dependent← claim 1GaNnon-polar or semi-polar GaN substrate
A gallium nitride substrate according to claim 1, wherein the averaged dislocation density is 1×104 cm⁻² or less.
4
Dependent← claim 1GaNnon-polar or semi-polar GaN substrate
A gallium nitride substrate according to claim 1, wherein an area of the first main surface is 1.0 cm2 or more.
5
Dependent← claim 1GaNnon-polar or semi-polar GaN substrate
A gallium nitride substrate according to claim 1, wherein a stacking fault density in the first main surface is 10 cm⁻¹ or less.
6
Dependent← claim 1GaNnon-polar or semi-polar GaN substrate
A gallium nitride substrate according to claim 1, wherein the first main surface is an M-plane.
7
Dependent← claim 1GaNnon-polar or semi-polar GaN substrate
A gallium nitride substrate according to claim 1, wherein the first main surface has a normal vector of which is tilted from <10-10> direction to c-axis direc-tion, and the normal vector is between <10-11> direction and <10-1-1> direction.
A method for manufacturing a nitride semiconductor crystal, comprising: growing a nitride semiconductor crystal on the first main surface of the gallium nitride substrate according to claim 1.
Device structures
Layer stacks claimed or described, ordered top of device to substrate.
non-polar or semi-polar GaN substrate
GaNsubstrate
semiconductor light-emitting device
GaNp-type layer
nitride semiconductor crystallight-emitting layer
GaNn-type layer
GaNsubstrate
Materials
Materials described outside the worked examples.
gallium nitride (GaN) substrate
GaN
Substrate
Epitaxial LayerBulk Crystal Source
nitride semiconductor crystal
Process steps
Additional fabrication and treatment steps described in the patent.
1
Hvpe Growth
Step 1
Process details
notes:Used to grow bulk GaN crystal for subsequent slicing into non-polar or semi-polar substrates
method:HVPE (Hydride Vapor Phase Epitaxy)
product:bulk GaN crystal
Materials:GaN
Characterization
Measurements and analyses referenced in the patent, with their drawing references.
thickness
Thickness
FIG. 4, a plate-like GaN crystal of which thickness direction is the m-axis direction is grown from the opening of the mask pattern. The secondary substrate …
GALLIUM NITRIDE SUBSTRATE AND MANUFACTURING METHOD OF NITRIDE SEMICONDUCTOR CRYSTAL
Yusuke Tsukada, Shuichi Kubo, Kazunori Kamada, Hideo Fujisawa et al.
MITSUBISHI CHEMICAL CORPORATION, Tokyo (JP)·Jun. 6, 2023·US
Drawings
Patent drawings and their descriptions. Click a drawing to enlarge it.
FIG. 1
FIGS. 1A and 1B, the substrate 1 has two main surfaces 11 parallel to each other and an edge surface 12. Chamfering can be performed, as necessary, for …
FIG. 2
FIG. 2. The crystal growth apparatus 2 depicted in
FIG. 3
FIG. 3. In the crystal growth apparatus 3 depicted in
FIG. 4
FIG. 4, a plate-like GaN crystal of which thickness direction is the m-axis direction is grown from the opening of the mask pattern. The secondary substrate …
FIG. 5
FIG. 5, the heating rate is constant from the heating step to the initial growth step. In the example of
FIG. 6
FIG. 6, between the heating step and the initial growth step, the temperature keeping step of keeping the substrate tem- perature constant is provided. The …
FIG. 7
FIG. 7, the heating rate is changed at the early and later stages of the initial growth step. In this example, the heating rate is changed discontinuously, but …
FIG. 8
FIG. 8 is a cross-sectional view, and the semiconductor light- emitting device 40A has a semiconductor laminate L grown 65 on the main surface of the GaN …
FIG. 9
FIG. 9 having a negative electrode 46 on the backside of the GaN substrate 41, the lowering effect of the operating voltage due to the increased carrier …
FIG. 10
FIG. 10 is a schematic diagram for explaining a structure of a GaN layer bonded substrate.
FIG. 11
FIG. 11 is a cross-sectional view depicting two seed substrates arranged on a susceptor. MODE FOR CARRYING OUT THE INVENTION The surface of a nitride …
Claims
Claims define the patent's legal scope. Independent claims stand alone; dependent claims (nested) narrow them. Click a claim to expand its dependents.
1 independent · 14 dependent
1
IndependentGaNnon-polar or semi-polar GaN substrate
A gallium nitride substrate comprising a first main surface and a second main surface opposite thereto, wherein the first main surface is a non-polar or semi-polar plane, a dislocation density measured by a room-temperature cathode luminescence method averaged over a whole of the first main surface is 1×104 cm⁻² or less, and an averaged dislocation density measured by a room-temperature cathode luminescence method in an arbi-trary selected square region sizing 250 µm×250 µm in the first main surface is 1×106 cm⁻² or less.
2
Dependent← claim 1GaNnon-polar or semi-polar GaN substrate
A gallium nitride substrate according to claim 1, wherein the dislocation density is 10 cm⁻² or less.
3
Dependent← claim 1GaNnon-polar or semi-polar GaN substrate
A gallium nitride substrate according to claim 1, wherein the averaged dislocation density is 1×104 cm⁻² or less.
4
Dependent← claim 1GaNnon-polar or semi-polar GaN substrate
A gallium nitride substrate according to claim 1, wherein an area of the first main surface is 1.0 cm2 or more.
5
Dependent← claim 1GaNnon-polar or semi-polar GaN substrate
A gallium nitride substrate according to claim 1, wherein a stacking fault density in the first main surface is 10 cm⁻¹ or less.
6
Dependent← claim 1GaNnon-polar or semi-polar GaN substrate
A gallium nitride substrate according to claim 1, wherein the first main surface is an M-plane.
7
Dependent← claim 1GaNnon-polar or semi-polar GaN substrate
A gallium nitride substrate according to claim 1, wherein the first main surface has a normal vector of which is tilted from <10-10> direction to c-axis direc-tion, and the normal vector is between <10-11> direction and <10-1-1> direction.
A method for manufacturing a nitride semiconductor crystal, comprising: growing a nitride semiconductor crystal on the first main surface of the gallium nitride substrate according to claim 1.
Device structures
Layer stacks claimed or described, ordered top of device to substrate.
non-polar or semi-polar GaN substrate
GaNsubstrate
semiconductor light-emitting device
GaNp-type layer
nitride semiconductor crystallight-emitting layer
GaNn-type layer
GaNsubstrate
Materials
Materials described outside the worked examples.
gallium nitride (GaN) substrate
GaN
Substrate
Epitaxial LayerBulk Crystal Source
nitride semiconductor crystal
Process steps
Additional fabrication and treatment steps described in the patent.
1
Hvpe Growth
Step 1
Process details
notes:Used to grow bulk GaN crystal for subsequent slicing into non-polar or semi-polar substrates
method:HVPE (Hydride Vapor Phase Epitaxy)
product:bulk GaN crystal
Materials:GaN
Characterization
Measurements and analyses referenced in the patent, with their drawing references.
thickness
Thickness
FIG. 4, a plate-like GaN crystal of which thickness direction is the m-axis direction is grown from the opening of the mask pattern. The secondary substrate …
product:nitride semiconductor crystal (bulk or thin film)
substrate:non-polar or semi-polar GaN substrate (mat001)
Materials:nitride semiconductor crystal
tem
TEM
FIG. 6, between the heating step and the initial growth step, the temperature keeping step of keeping the substrate tem- perature constant is provided. The …
dislocation density (whole surface)-tighter limit from claim 2
≤ 10 cm⁻²
GaN
averaged dislocation density in 250 µm × 250 µm region-tighter limit from claim 3
≤ 10000 cm⁻²
GaN
stacking fault density (second aspect, M-plane substrate with high carrier density)
≤ 100 cm⁻¹
GaN
carrier density (second aspect GaN substrate, M-plane)
≥ 3000000000000000000 cm⁻³
GaN
oxygen concentration (second aspect GaN substrate)
≥ 4000000000000000000 cm⁻³
GaN
2008/0001165 A1 1/2008 Hashimoto
US 2009/0078944 A12009/0078944 A1 3/2009 Kubota
US 2011/0073871 A12011/0073871 A1 3/2011 Hachigo
US 2011/0108852 A12011/0108852 A1 * 5/2011 Fujiwara................. C30B 25/00examiner
US 2011/0147759 A12011/0147759 A1 6/2011 Oshima
US 2011/0163326 A12011/0163326 A1 7/2011 Matsumoto
US 2012/0000415 A12012/0000415 A1 1/2012 D’Evelyn et al.
US 2012/0074403 A12012/0074403 A1 3/2012 Fujiwara et al.
US 2013/0119401 A12013/0119401 A1 5/2013 D’Evelyn et al.
US 2013/0137220 A12013/0137220 A1 * 5/2013 Matsubara.............. H01L 21/50examiner
US 2013/0264606 A12013/0264606 A1 10/2013 Kubo et al.
US 2014/0065360 A12014/0065360 A1 3/2014 D’Evelyn
US 2015/0093318 A12015/0093318 A1 4/2015 Enatsu et al.
Cited non-patent literature · 2
P-type conduction in stacking-fault-free m-plane GaN. Melvin McLaurin et al., “P-type conduction in stacking-fault-free m-plane GaN”, Physica Status Solidi (RRL), vol. 1, No. 3, p. 110-112 (2007).
Kenji Fujito et al., High-quality nonpolar m-plane GaN substrates grown by HVPE, phys. stat. sol. (a), vol. 205, No. 5, p. 1056-1059 (2008). International Search Report dated Mar. 18, 2014 in PCT/JP2013/083110 filed Dec. 10, 2013. International Preliminary Report on Patentability and Written Opin- ion dated Jul. 2, 2015 in PCT/JP2013/083110 filed Dec. 10, 2013. Japanese Office Action dated Mar. 24, 2020, in Japanese Patent Application No. 2019-019494 (with English Translation).
product:nitride semiconductor crystal (bulk or thin film)
substrate:non-polar or semi-polar GaN substrate (mat001)
Materials:nitride semiconductor crystal
tem
TEM
FIG. 6, between the heating step and the initial growth step, the temperature keeping step of keeping the substrate tem- perature constant is provided. The …
dislocation density (whole surface)-tighter limit from claim 2
≤ 10 cm⁻²
GaN
averaged dislocation density in 250 µm × 250 µm region-tighter limit from claim 3
≤ 10000 cm⁻²
GaN
stacking fault density (second aspect, M-plane substrate with high carrier density)
≤ 100 cm⁻¹
GaN
carrier density (second aspect GaN substrate, M-plane)
≥ 3000000000000000000 cm⁻³
GaN
oxygen concentration (second aspect GaN substrate)
≥ 4000000000000000000 cm⁻³
GaN
2008/0001165 A1 1/2008 Hashimoto
US 2009/0078944 A12009/0078944 A1 3/2009 Kubota
US 2011/0073871 A12011/0073871 A1 3/2011 Hachigo
US 2011/0108852 A12011/0108852 A1 * 5/2011 Fujiwara................. C30B 25/00examiner
US 2011/0147759 A12011/0147759 A1 6/2011 Oshima
US 2011/0163326 A12011/0163326 A1 7/2011 Matsumoto
US 2012/0000415 A12012/0000415 A1 1/2012 D’Evelyn et al.
US 2012/0074403 A12012/0074403 A1 3/2012 Fujiwara et al.
US 2013/0119401 A12013/0119401 A1 5/2013 D’Evelyn et al.
US 2013/0137220 A12013/0137220 A1 * 5/2013 Matsubara.............. H01L 21/50examiner
US 2013/0264606 A12013/0264606 A1 10/2013 Kubo et al.
US 2014/0065360 A12014/0065360 A1 3/2014 D’Evelyn
US 2015/0093318 A12015/0093318 A1 4/2015 Enatsu et al.
Cited non-patent literature · 2
P-type conduction in stacking-fault-free m-plane GaN. Melvin McLaurin et al., “P-type conduction in stacking-fault-free m-plane GaN”, Physica Status Solidi (RRL), vol. 1, No. 3, p. 110-112 (2007).
Kenji Fujito et al., High-quality nonpolar m-plane GaN substrates grown by HVPE, phys. stat. sol. (a), vol. 205, No. 5, p. 1056-1059 (2008). International Search Report dated Mar. 18, 2014 in PCT/JP2013/083110 filed Dec. 10, 2013. International Preliminary Report on Patentability and Written Opin- ion dated Jul. 2, 2015 in PCT/JP2013/083110 filed Dec. 10, 2013. Japanese Office Action dated Mar. 24, 2020, in Japanese Patent Application No. 2019-019494 (with English Translation).
product:nitride semiconductor crystal (bulk or thin film)
substrate:non-polar or semi-polar GaN substrate (mat001)
Materials:nitride semiconductor crystal
tem
TEM
FIG. 6, between the heating step and the initial growth step, the temperature keeping step of keeping the substrate tem- perature constant is provided. The …
dislocation density (whole surface)-tighter limit from claim 2
≤ 10 cm⁻²
GaN
averaged dislocation density in 250 µm × 250 µm region-tighter limit from claim 3
≤ 10000 cm⁻²
GaN
stacking fault density (second aspect, M-plane substrate with high carrier density)
≤ 100 cm⁻¹
GaN
carrier density (second aspect GaN substrate, M-plane)
≥ 3000000000000000000 cm⁻³
GaN
oxygen concentration (second aspect GaN substrate)
≥ 4000000000000000000 cm⁻³
GaN
2008/0001165 A1 1/2008 Hashimoto
US 2009/0078944 A12009/0078944 A1 3/2009 Kubota
US 2011/0073871 A12011/0073871 A1 3/2011 Hachigo
US 2011/0108852 A12011/0108852 A1 * 5/2011 Fujiwara................. C30B 25/00examiner
US 2011/0147759 A12011/0147759 A1 6/2011 Oshima
US 2011/0163326 A12011/0163326 A1 7/2011 Matsumoto
US 2012/0000415 A12012/0000415 A1 1/2012 D’Evelyn et al.
US 2012/0074403 A12012/0074403 A1 3/2012 Fujiwara et al.
US 2013/0119401 A12013/0119401 A1 5/2013 D’Evelyn et al.
US 2013/0137220 A12013/0137220 A1 * 5/2013 Matsubara.............. H01L 21/50examiner
US 2013/0264606 A12013/0264606 A1 10/2013 Kubo et al.
US 2014/0065360 A12014/0065360 A1 3/2014 D’Evelyn
US 2015/0093318 A12015/0093318 A1 4/2015 Enatsu et al.
Cited non-patent literature · 2
P-type conduction in stacking-fault-free m-plane GaN. Melvin McLaurin et al., “P-type conduction in stacking-fault-free m-plane GaN”, Physica Status Solidi (RRL), vol. 1, No. 3, p. 110-112 (2007).
Kenji Fujito et al., High-quality nonpolar m-plane GaN substrates grown by HVPE, phys. stat. sol. (a), vol. 205, No. 5, p. 1056-1059 (2008). International Search Report dated Mar. 18, 2014 in PCT/JP2013/083110 filed Dec. 10, 2013. International Preliminary Report on Patentability and Written Opin- ion dated Jul. 2, 2015 in PCT/JP2013/083110 filed Dec. 10, 2013. Japanese Office Action dated Mar. 24, 2020, in Japanese Patent Application No. 2019-019494 (with English Translation).
product:nitride semiconductor crystal (bulk or thin film)
substrate:non-polar or semi-polar GaN substrate (mat001)
Materials:nitride semiconductor crystal
tem
TEM
FIG. 6, between the heating step and the initial growth step, the temperature keeping step of keeping the substrate tem- perature constant is provided. The …
dislocation density (whole surface)-tighter limit from claim 2
≤ 10 cm⁻²
GaN
averaged dislocation density in 250 µm × 250 µm region-tighter limit from claim 3
≤ 10000 cm⁻²
GaN
stacking fault density (second aspect, M-plane substrate with high carrier density)
≤ 100 cm⁻¹
GaN
carrier density (second aspect GaN substrate, M-plane)
≥ 3000000000000000000 cm⁻³
GaN
oxygen concentration (second aspect GaN substrate)
≥ 4000000000000000000 cm⁻³
GaN
2008/0001165 A1 1/2008 Hashimoto
US 2009/0078944 A12009/0078944 A1 3/2009 Kubota
US 2011/0073871 A12011/0073871 A1 3/2011 Hachigo
US 2011/0108852 A12011/0108852 A1 * 5/2011 Fujiwara................. C30B 25/00examiner
US 2011/0147759 A12011/0147759 A1 6/2011 Oshima
US 2011/0163326 A12011/0163326 A1 7/2011 Matsumoto
US 2012/0000415 A12012/0000415 A1 1/2012 D’Evelyn et al.
US 2012/0074403 A12012/0074403 A1 3/2012 Fujiwara et al.
US 2013/0119401 A12013/0119401 A1 5/2013 D’Evelyn et al.
US 2013/0137220 A12013/0137220 A1 * 5/2013 Matsubara.............. H01L 21/50examiner
US 2013/0264606 A12013/0264606 A1 10/2013 Kubo et al.
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