ATOMIC LAYER DEPOSITION OF BARRIER METAL LAYER FOR ELECTRODE OF GALLIUM NITRIDE MATERIAL DEVICE | Matter42 Literature
Patent
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Patent
US 12,112,983 B2
ATOMIC LAYER DEPOSITION OF BARRIER METAL LAYER FOR ELECTRODE OF GALLIUM NITRIDE MATERIAL DEVICE
Timothy E. Boles, Wayne Mack Struble, Gabriel R. Cueva
MACOM TECHNOLOGY SOLUTIONS HOLDINGS, INC., Lowell, MA (US)·Oct. 8, 2024·US
Drawings
Patent drawings and their descriptions. Click a drawing to enlarge it.
FIG. 1
FIG. 1 illustrates an example electrode structure for a device according to various embodiments described herein.
FIG. 2
FIG. 2 illustrates an example method of forming the electrode structure shown in
FIG. 3
FIG. 3 illustrates an example substrate and insulating dielectric layer according to various embodiments described herein.
FIG. 4
FIG. 4 illustrates an example opening in the insulating dielectric layer shown in
FIG. 5
FIG. 5 illustrates an example barrier metal layer formed over the insulating dielectric layer and the surface region of the substrate according to various …
FIG. 6
FIG. 6 illustrates an example conducting metal layer formed over the barrier metal layer according to various embodiments described herein.
FIG. 7
FIG. 7 illustrates an example cap metal layer formed over the conducting metal layer according to various embodi- ments described herein.
FIG. 8
FIG. 8 illustrates an mask layer formed over the cap metal layer according to various embodiments described herein.
FIG. 9
FIG. 9 illustrates an example electrode structure formed by etching the barrier layer, the conducting layer, and the cap metal layer around the mask layer …
FIG. 10
FIG. 10 illustrates an example electrode structure formed after removing the mask layer according to various embodi- ments described herein.
Claims
Claims define the patent's legal scope. Independent claims stand alone; dependent claims (nested) narrow them. Click a claim to expand its dependents.
3 independent · 16 dependent
1
Independentbarrier metal layerconducting metal layercap metal layerinsulating layerelectrode structure for GaN material device
A method of manufacturing an electrode structure for a device, comprising: forming an insulating layer over a surface of a substrate; forming an opening in the insulating layer to expose a semiconductor material surface region of the substrate through the opening; depositing a barrier metal layer over the insulating layer and onto the semiconductor material surface region of the substrate through the opening in the insulating layer using atomic layer deposition; depositing a conducting metal layer over the barrier metal layer; depositing a cap metal layer over the conducting metal layer using sputtering; forming a cap etch photoresist layer over a region of the cap metal layer; and etching the cap metal layer, the conducting metal layer, and the barrier metal layer down to the insulating layer over an area outside of the cap etch photoresist layer.
2
Dependent← claim 1barrier metal layer
The method according to claim 1, wherein depositing the barrier metal layer comprises depositing the barrier metal layer onto the insulating layer and onto the semicon-ductor material surface region of the substrate using atomic layer deposition.
3
Dependent← claim 1WN
The method according to claim 1, wherein the barrier metal layer comprises tungsten nitride.
4
Dependent← claim 1conducting metal layer
The method according to claim 1, wherein depositing the conductive metal layer comprises sputtering the conduc-tive metal layer over the barrier metal layer.
5
Dependent← claim 1Al
The method according to claim 1, wherein the con-ducting metal layer comprises aluminum.
6
Dependent← claim 1TiNWWN
The method according to claim 1, wherein the cap metal layer comprises at least one of titanium nitride, tungsten, and tungsten nitride.
7
Dependent← claim 1
The method according to claim 1, further comprising removing the cap etch photoresist layer.
8
Dependent← claim 1GaNbarrier metal layer
The method according to claim 1, wherein: the substrate comprises a gallium nitride material layer; forming the opening in the insulating layer comprises exposing a surface region of the gallium nitride mate-rial layer; and depositing the barrier metal layer comprises depositing the barrier metal layer onto the surface region of the gallium nitride material layer.
9
IndependentGaNbarrier metal layerconducting metal layerTiNWWNelectrode structure for GaN material device
A method of manufacturing an electrode structure for a device, comprising: providing a substrate comprising a gallium nitride mate-rial layer; forming an insulating layer over a surface of the gallium nitride material layer; forming an opening in the insulating layer to expose a surface region of the gallium nitride material layer through the opening; depositing a barrier metal layer over the insulating layer and onto the surface region of the gallium nitride material layer through the opening in the insulating layer using atomic layer deposition; depositing a conducting metal layer over the barrier metal layer; and depositing a cap metal layer of at least one of titanium nitride, tungsten, and tungsten nitride over the conduct-ing metal layer using sputtering.
10
Dependent← claim 9WN
The method according to claim 9, wherein the barrier metal layer comprises tungsten nitride.
11
Dependent← claim 9conducting metal layer
The method according to claim 9, wherein depositing the conductive metal layer comprises sputtering the conduc-tive metal layer over the barrier metal layer.
12
Dependent← claim 9Al
The method according to claim 9, wherein the con-ducting metal layer comprises aluminum.
13
Independentbarrier metal layerconducting metal layercap metal layerelectrode structure for GaN material device
A method of manufacturing an electrode structure for a device, comprising: forming an opening in an insulating layer to expose a semiconductor material surface region of a substrate through the opening; depositing a barrier metal layer over the insulating layer and onto the semiconductor material surface region of the substrate through the opening using atomic layer deposition; depositing a conducting metal layer over the barrier metal layer using sputtering; depositing a cap metal layer over the conducting metal layer using sputtering; and etching the cap metal layer, the conducting metal layer, and the barrier metal layer down to the insulating layer over an area.
14
Dependent← claim 13GaNbarrier metal layer
The method according to claim 13, wherein: the substrate comprises a gallium nitride material layer; forming the opening in the insulating layer comprises exposing a surface region of the gallium nitride mate-rial layer; and depositing the barrier metal layer comprises depositing the barrier metal layer onto the surface region of the gallium nitride material layer.
15
Dependent← claim 13Al
The method according to claim 13, wherein the conducting metal layer comprises aluminum.
16
Dependent← claim 13TiNWWN
The method according to claim 13, wherein the cap metal layer comprises at least one of titanium nitride, tungsten, and tungsten nitride. 11 12
17
Dependent← claim 13WN
The method according to claim 13, wherein the barrier metal layer comprises tungsten nitride.
18
Dependent← claim 13WNAlTiNW
The method according to claim 13, wherein: the barrier metal layer comprises tungsten nitride; the conducting metal layer comprises aluminum; and the cap metal layer comprises at least one of titanium nitride, tungsten, and tungsten nitride.
19
Dependent← claim 13barrier metal layer
The method according to claim 13, wherein depositing the barrier metal layer comprises depositing the barrier metal layer onto the insulating layer and onto the semicon-ductor material surface region of the substrate using atomic layer deposition. ∗ ∗ ∗ ∗ ∗
Device structures
Layer stacks claimed or described, ordered top of device to substrate.
electrode structure for GaN material device
TiNcap metal layer
Alconducting metal layer
WNbarrier metal layer
insulating layerinsulating layer
GaNsubstrate
Materials
Materials described outside the worked examples.
barrier metal layer
Barrier Metal Layer Deposited By ALD
conducting metal layer
Conducting Metal Layer In Electrode Stack
Process steps
Additional fabrication and treatment steps described in the patent.
1
Ald Deposition
Step 1
Process details
method:atomic layer deposition
deposited on:insulating layer and semiconductor material surface region through opening
Materials:WN
2
Reported properties
Performance values and ranges asserted in the specification or claims.
Property
Value
Material
Thickness
900–1025 Å
—
Thickness
Cited prior art
Patents and literature cited by this patent (applicant and examiner references).
Cited patents · 21
US 11,398,406 B211,398,406 B2 * 7/2022 Kuo.................. H01L 23/53238examiner
US 11,508,667 B111,508,667 B1 * 11/2022 Karp....................... H01L 23/50examiner
CN 111326574 ACN 111326574 A 6/2020
CN 114078815 ACN 114078815 A * 2/2022....... H01L 21/76802examiner
Why these are connected
Related documents with shared materials, methods, properties, or citations.
ATOMIC LAYER DEPOSITION OF BARRIER METAL LAYER FOR ELECTRODE OF GALLIUM NITRIDE MATERIAL DEVICE
Timothy E. Boles, Wayne Mack Struble, Gabriel R. Cueva
MACOM TECHNOLOGY SOLUTIONS HOLDINGS, INC., Lowell, MA (US)·Oct. 8, 2024·US
Drawings
Patent drawings and their descriptions. Click a drawing to enlarge it.
FIG. 1
FIG. 1 illustrates an example electrode structure for a device according to various embodiments described herein.
FIG. 2
FIG. 2 illustrates an example method of forming the electrode structure shown in
FIG. 3
FIG. 3 illustrates an example substrate and insulating dielectric layer according to various embodiments described herein.
FIG. 4
FIG. 4 illustrates an example opening in the insulating dielectric layer shown in
FIG. 5
FIG. 5 illustrates an example barrier metal layer formed over the insulating dielectric layer and the surface region of the substrate according to various …
FIG. 6
FIG. 6 illustrates an example conducting metal layer formed over the barrier metal layer according to various embodiments described herein.
FIG. 7
FIG. 7 illustrates an example cap metal layer formed over the conducting metal layer according to various embodi- ments described herein.
FIG. 8
FIG. 8 illustrates an mask layer formed over the cap metal layer according to various embodiments described herein.
FIG. 9
FIG. 9 illustrates an example electrode structure formed by etching the barrier layer, the conducting layer, and the cap metal layer around the mask layer …
FIG. 10
FIG. 10 illustrates an example electrode structure formed after removing the mask layer according to various embodi- ments described herein.
Claims
Claims define the patent's legal scope. Independent claims stand alone; dependent claims (nested) narrow them. Click a claim to expand its dependents.
3 independent · 16 dependent
1
Independentbarrier metal layerconducting metal layercap metal layerinsulating layerelectrode structure for GaN material device
A method of manufacturing an electrode structure for a device, comprising: forming an insulating layer over a surface of a substrate; forming an opening in the insulating layer to expose a semiconductor material surface region of the substrate through the opening; depositing a barrier metal layer over the insulating layer and onto the semiconductor material surface region of the substrate through the opening in the insulating layer using atomic layer deposition; depositing a conducting metal layer over the barrier metal layer; depositing a cap metal layer over the conducting metal layer using sputtering; forming a cap etch photoresist layer over a region of the cap metal layer; and etching the cap metal layer, the conducting metal layer, and the barrier metal layer down to the insulating layer over an area outside of the cap etch photoresist layer.
2
Dependent← claim 1barrier metal layer
The method according to claim 1, wherein depositing the barrier metal layer comprises depositing the barrier metal layer onto the insulating layer and onto the semicon-ductor material surface region of the substrate using atomic layer deposition.
3
Dependent← claim 1WN
The method according to claim 1, wherein the barrier metal layer comprises tungsten nitride.
4
Dependent← claim 1conducting metal layer
The method according to claim 1, wherein depositing the conductive metal layer comprises sputtering the conduc-tive metal layer over the barrier metal layer.
5
Dependent← claim 1Al
The method according to claim 1, wherein the con-ducting metal layer comprises aluminum.
6
Dependent← claim 1TiNWWN
The method according to claim 1, wherein the cap metal layer comprises at least one of titanium nitride, tungsten, and tungsten nitride.
7
Dependent← claim 1
The method according to claim 1, further comprising removing the cap etch photoresist layer.
8
Dependent← claim 1GaNbarrier metal layer
The method according to claim 1, wherein: the substrate comprises a gallium nitride material layer; forming the opening in the insulating layer comprises exposing a surface region of the gallium nitride mate-rial layer; and depositing the barrier metal layer comprises depositing the barrier metal layer onto the surface region of the gallium nitride material layer.
9
IndependentGaNbarrier metal layerconducting metal layerTiNWWNelectrode structure for GaN material device
A method of manufacturing an electrode structure for a device, comprising: providing a substrate comprising a gallium nitride mate-rial layer; forming an insulating layer over a surface of the gallium nitride material layer; forming an opening in the insulating layer to expose a surface region of the gallium nitride material layer through the opening; depositing a barrier metal layer over the insulating layer and onto the surface region of the gallium nitride material layer through the opening in the insulating layer using atomic layer deposition; depositing a conducting metal layer over the barrier metal layer; and depositing a cap metal layer of at least one of titanium nitride, tungsten, and tungsten nitride over the conduct-ing metal layer using sputtering.
10
Dependent← claim 9WN
The method according to claim 9, wherein the barrier metal layer comprises tungsten nitride.
11
Dependent← claim 9conducting metal layer
The method according to claim 9, wherein depositing the conductive metal layer comprises sputtering the conduc-tive metal layer over the barrier metal layer.
12
Dependent← claim 9Al
The method according to claim 9, wherein the con-ducting metal layer comprises aluminum.
13
Independentbarrier metal layerconducting metal layercap metal layerelectrode structure for GaN material device
A method of manufacturing an electrode structure for a device, comprising: forming an opening in an insulating layer to expose a semiconductor material surface region of a substrate through the opening; depositing a barrier metal layer over the insulating layer and onto the semiconductor material surface region of the substrate through the opening using atomic layer deposition; depositing a conducting metal layer over the barrier metal layer using sputtering; depositing a cap metal layer over the conducting metal layer using sputtering; and etching the cap metal layer, the conducting metal layer, and the barrier metal layer down to the insulating layer over an area.
14
Dependent← claim 13GaNbarrier metal layer
The method according to claim 13, wherein: the substrate comprises a gallium nitride material layer; forming the opening in the insulating layer comprises exposing a surface region of the gallium nitride mate-rial layer; and depositing the barrier metal layer comprises depositing the barrier metal layer onto the surface region of the gallium nitride material layer.
15
Dependent← claim 13Al
The method according to claim 13, wherein the conducting metal layer comprises aluminum.
16
Dependent← claim 13TiNWWN
The method according to claim 13, wherein the cap metal layer comprises at least one of titanium nitride, tungsten, and tungsten nitride. 11 12
17
Dependent← claim 13WN
The method according to claim 13, wherein the barrier metal layer comprises tungsten nitride.
18
Dependent← claim 13WNAlTiNW
The method according to claim 13, wherein: the barrier metal layer comprises tungsten nitride; the conducting metal layer comprises aluminum; and the cap metal layer comprises at least one of titanium nitride, tungsten, and tungsten nitride.
19
Dependent← claim 13barrier metal layer
The method according to claim 13, wherein depositing the barrier metal layer comprises depositing the barrier metal layer onto the insulating layer and onto the semicon-ductor material surface region of the substrate using atomic layer deposition. ∗ ∗ ∗ ∗ ∗
Device structures
Layer stacks claimed or described, ordered top of device to substrate.
electrode structure for GaN material device
TiNcap metal layer
Alconducting metal layer
WNbarrier metal layer
insulating layerinsulating layer
GaNsubstrate
Materials
Materials described outside the worked examples.
barrier metal layer
Barrier Metal Layer Deposited By ALD
conducting metal layer
Conducting Metal Layer In Electrode Stack
Process steps
Additional fabrication and treatment steps described in the patent.
1
Ald Deposition
Step 1
Process details
method:atomic layer deposition
deposited on:insulating layer and semiconductor material surface region through opening
Materials:WN
2
Reported properties
Performance values and ranges asserted in the specification or claims.
Property
Value
Material
Thickness
900–1025 Å
—
Thickness
Cited prior art
Patents and literature cited by this patent (applicant and examiner references).
Cited patents · 21
US 11,398,406 B211,398,406 B2 * 7/2022 Kuo.................. H01L 23/53238examiner
US 11,508,667 B111,508,667 B1 * 11/2022 Karp....................... H01L 23/50examiner
CN 111326574 ACN 111326574 A 6/2020
CN 114078815 ACN 114078815 A * 2/2022....... H01L 21/76802examiner
Why these are connected
Related documents with shared materials, methods, properties, or citations.
ATOMIC LAYER DEPOSITION OF BARRIER METAL LAYER FOR ELECTRODE OF GALLIUM NITRIDE MATERIAL DEVICE
Timothy E. Boles, Wayne Mack Struble, Gabriel R. Cueva
MACOM TECHNOLOGY SOLUTIONS HOLDINGS, INC., Lowell, MA (US)·Oct. 8, 2024·US
Drawings
Patent drawings and their descriptions. Click a drawing to enlarge it.
FIG. 1
FIG. 1 illustrates an example electrode structure for a device according to various embodiments described herein.
FIG. 2
FIG. 2 illustrates an example method of forming the electrode structure shown in
FIG. 3
FIG. 3 illustrates an example substrate and insulating dielectric layer according to various embodiments described herein.
FIG. 4
FIG. 4 illustrates an example opening in the insulating dielectric layer shown in
FIG. 5
FIG. 5 illustrates an example barrier metal layer formed over the insulating dielectric layer and the surface region of the substrate according to various …
FIG. 6
FIG. 6 illustrates an example conducting metal layer formed over the barrier metal layer according to various embodiments described herein.
FIG. 7
FIG. 7 illustrates an example cap metal layer formed over the conducting metal layer according to various embodi- ments described herein.
FIG. 8
FIG. 8 illustrates an mask layer formed over the cap metal layer according to various embodiments described herein.
FIG. 9
FIG. 9 illustrates an example electrode structure formed by etching the barrier layer, the conducting layer, and the cap metal layer around the mask layer …
FIG. 10
FIG. 10 illustrates an example electrode structure formed after removing the mask layer according to various embodi- ments described herein.
Claims
Claims define the patent's legal scope. Independent claims stand alone; dependent claims (nested) narrow them. Click a claim to expand its dependents.
3 independent · 16 dependent
1
Independentbarrier metal layerconducting metal layercap metal layerinsulating layerelectrode structure for GaN material device
A method of manufacturing an electrode structure for a device, comprising: forming an insulating layer over a surface of a substrate; forming an opening in the insulating layer to expose a semiconductor material surface region of the substrate through the opening; depositing a barrier metal layer over the insulating layer and onto the semiconductor material surface region of the substrate through the opening in the insulating layer using atomic layer deposition; depositing a conducting metal layer over the barrier metal layer; depositing a cap metal layer over the conducting metal layer using sputtering; forming a cap etch photoresist layer over a region of the cap metal layer; and etching the cap metal layer, the conducting metal layer, and the barrier metal layer down to the insulating layer over an area outside of the cap etch photoresist layer.
2
Dependent← claim 1barrier metal layer
The method according to claim 1, wherein depositing the barrier metal layer comprises depositing the barrier metal layer onto the insulating layer and onto the semicon-ductor material surface region of the substrate using atomic layer deposition.
3
Dependent← claim 1WN
The method according to claim 1, wherein the barrier metal layer comprises tungsten nitride.
4
Dependent← claim 1conducting metal layer
The method according to claim 1, wherein depositing the conductive metal layer comprises sputtering the conduc-tive metal layer over the barrier metal layer.
5
Dependent← claim 1Al
The method according to claim 1, wherein the con-ducting metal layer comprises aluminum.
6
Dependent← claim 1TiNWWN
The method according to claim 1, wherein the cap metal layer comprises at least one of titanium nitride, tungsten, and tungsten nitride.
7
Dependent← claim 1
The method according to claim 1, further comprising removing the cap etch photoresist layer.
8
Dependent← claim 1GaNbarrier metal layer
The method according to claim 1, wherein: the substrate comprises a gallium nitride material layer; forming the opening in the insulating layer comprises exposing a surface region of the gallium nitride mate-rial layer; and depositing the barrier metal layer comprises depositing the barrier metal layer onto the surface region of the gallium nitride material layer.
9
IndependentGaNbarrier metal layerconducting metal layerTiNWWNelectrode structure for GaN material device
A method of manufacturing an electrode structure for a device, comprising: providing a substrate comprising a gallium nitride mate-rial layer; forming an insulating layer over a surface of the gallium nitride material layer; forming an opening in the insulating layer to expose a surface region of the gallium nitride material layer through the opening; depositing a barrier metal layer over the insulating layer and onto the surface region of the gallium nitride material layer through the opening in the insulating layer using atomic layer deposition; depositing a conducting metal layer over the barrier metal layer; and depositing a cap metal layer of at least one of titanium nitride, tungsten, and tungsten nitride over the conduct-ing metal layer using sputtering.
10
Dependent← claim 9WN
The method according to claim 9, wherein the barrier metal layer comprises tungsten nitride.
11
Dependent← claim 9conducting metal layer
The method according to claim 9, wherein depositing the conductive metal layer comprises sputtering the conduc-tive metal layer over the barrier metal layer.
12
Dependent← claim 9Al
The method according to claim 9, wherein the con-ducting metal layer comprises aluminum.
13
Independentbarrier metal layerconducting metal layercap metal layerelectrode structure for GaN material device
A method of manufacturing an electrode structure for a device, comprising: forming an opening in an insulating layer to expose a semiconductor material surface region of a substrate through the opening; depositing a barrier metal layer over the insulating layer and onto the semiconductor material surface region of the substrate through the opening using atomic layer deposition; depositing a conducting metal layer over the barrier metal layer using sputtering; depositing a cap metal layer over the conducting metal layer using sputtering; and etching the cap metal layer, the conducting metal layer, and the barrier metal layer down to the insulating layer over an area.
14
Dependent← claim 13GaNbarrier metal layer
The method according to claim 13, wherein: the substrate comprises a gallium nitride material layer; forming the opening in the insulating layer comprises exposing a surface region of the gallium nitride mate-rial layer; and depositing the barrier metal layer comprises depositing the barrier metal layer onto the surface region of the gallium nitride material layer.
15
Dependent← claim 13Al
The method according to claim 13, wherein the conducting metal layer comprises aluminum.
16
Dependent← claim 13TiNWWN
The method according to claim 13, wherein the cap metal layer comprises at least one of titanium nitride, tungsten, and tungsten nitride. 11 12
17
Dependent← claim 13WN
The method according to claim 13, wherein the barrier metal layer comprises tungsten nitride.
18
Dependent← claim 13WNAlTiNW
The method according to claim 13, wherein: the barrier metal layer comprises tungsten nitride; the conducting metal layer comprises aluminum; and the cap metal layer comprises at least one of titanium nitride, tungsten, and tungsten nitride.
19
Dependent← claim 13barrier metal layer
The method according to claim 13, wherein depositing the barrier metal layer comprises depositing the barrier metal layer onto the insulating layer and onto the semicon-ductor material surface region of the substrate using atomic layer deposition. ∗ ∗ ∗ ∗ ∗
Device structures
Layer stacks claimed or described, ordered top of device to substrate.
electrode structure for GaN material device
TiNcap metal layer
Alconducting metal layer
WNbarrier metal layer
insulating layerinsulating layer
GaNsubstrate
Materials
Materials described outside the worked examples.
barrier metal layer
Barrier Metal Layer Deposited By ALD
conducting metal layer
Conducting Metal Layer In Electrode Stack
Process steps
Additional fabrication and treatment steps described in the patent.
1
Ald Deposition
Step 1
Process details
method:atomic layer deposition
deposited on:insulating layer and semiconductor material surface region through opening
Materials:WN
2
Reported properties
Performance values and ranges asserted in the specification or claims.
Property
Value
Material
Thickness
900–1025 Å
—
Thickness
Cited prior art
Patents and literature cited by this patent (applicant and examiner references).
Cited patents · 21
US 11,398,406 B211,398,406 B2 * 7/2022 Kuo.................. H01L 23/53238examiner
US 11,508,667 B111,508,667 B1 * 11/2022 Karp....................... H01L 23/50examiner
CN 111326574 ACN 111326574 A 6/2020
CN 114078815 ACN 114078815 A * 2/2022....... H01L 21/76802examiner
Why these are connected
Related documents with shared materials, methods, properties, or citations.
ATOMIC LAYER DEPOSITION OF BARRIER METAL LAYER FOR ELECTRODE OF GALLIUM NITRIDE MATERIAL DEVICE
Timothy E. Boles, Wayne Mack Struble, Gabriel R. Cueva
MACOM TECHNOLOGY SOLUTIONS HOLDINGS, INC., Lowell, MA (US)·Oct. 8, 2024·US
Drawings
Patent drawings and their descriptions. Click a drawing to enlarge it.
FIG. 1
FIG. 1 illustrates an example electrode structure for a device according to various embodiments described herein.
FIG. 2
FIG. 2 illustrates an example method of forming the electrode structure shown in
FIG. 3
FIG. 3 illustrates an example substrate and insulating dielectric layer according to various embodiments described herein.
FIG. 4
FIG. 4 illustrates an example opening in the insulating dielectric layer shown in
FIG. 5
FIG. 5 illustrates an example barrier metal layer formed over the insulating dielectric layer and the surface region of the substrate according to various …
FIG. 6
FIG. 6 illustrates an example conducting metal layer formed over the barrier metal layer according to various embodiments described herein.
FIG. 7
FIG. 7 illustrates an example cap metal layer formed over the conducting metal layer according to various embodi- ments described herein.
FIG. 8
FIG. 8 illustrates an mask layer formed over the cap metal layer according to various embodiments described herein.
FIG. 9
FIG. 9 illustrates an example electrode structure formed by etching the barrier layer, the conducting layer, and the cap metal layer around the mask layer …
FIG. 10
FIG. 10 illustrates an example electrode structure formed after removing the mask layer according to various embodi- ments described herein.
Claims
Claims define the patent's legal scope. Independent claims stand alone; dependent claims (nested) narrow them. Click a claim to expand its dependents.
3 independent · 16 dependent
1
Independentbarrier metal layerconducting metal layercap metal layerinsulating layerelectrode structure for GaN material device
A method of manufacturing an electrode structure for a device, comprising: forming an insulating layer over a surface of a substrate; forming an opening in the insulating layer to expose a semiconductor material surface region of the substrate through the opening; depositing a barrier metal layer over the insulating layer and onto the semiconductor material surface region of the substrate through the opening in the insulating layer using atomic layer deposition; depositing a conducting metal layer over the barrier metal layer; depositing a cap metal layer over the conducting metal layer using sputtering; forming a cap etch photoresist layer over a region of the cap metal layer; and etching the cap metal layer, the conducting metal layer, and the barrier metal layer down to the insulating layer over an area outside of the cap etch photoresist layer.
2
Dependent← claim 1barrier metal layer
The method according to claim 1, wherein depositing the barrier metal layer comprises depositing the barrier metal layer onto the insulating layer and onto the semicon-ductor material surface region of the substrate using atomic layer deposition.
3
Dependent← claim 1WN
The method according to claim 1, wherein the barrier metal layer comprises tungsten nitride.
4
Dependent← claim 1conducting metal layer
The method according to claim 1, wherein depositing the conductive metal layer comprises sputtering the conduc-tive metal layer over the barrier metal layer.
5
Dependent← claim 1Al
The method according to claim 1, wherein the con-ducting metal layer comprises aluminum.
6
Dependent← claim 1TiNWWN
The method according to claim 1, wherein the cap metal layer comprises at least one of titanium nitride, tungsten, and tungsten nitride.
7
Dependent← claim 1
The method according to claim 1, further comprising removing the cap etch photoresist layer.
8
Dependent← claim 1GaNbarrier metal layer
The method according to claim 1, wherein: the substrate comprises a gallium nitride material layer; forming the opening in the insulating layer comprises exposing a surface region of the gallium nitride mate-rial layer; and depositing the barrier metal layer comprises depositing the barrier metal layer onto the surface region of the gallium nitride material layer.
9
IndependentGaNbarrier metal layerconducting metal layerTiNWWNelectrode structure for GaN material device
A method of manufacturing an electrode structure for a device, comprising: providing a substrate comprising a gallium nitride mate-rial layer; forming an insulating layer over a surface of the gallium nitride material layer; forming an opening in the insulating layer to expose a surface region of the gallium nitride material layer through the opening; depositing a barrier metal layer over the insulating layer and onto the surface region of the gallium nitride material layer through the opening in the insulating layer using atomic layer deposition; depositing a conducting metal layer over the barrier metal layer; and depositing a cap metal layer of at least one of titanium nitride, tungsten, and tungsten nitride over the conduct-ing metal layer using sputtering.
10
Dependent← claim 9WN
The method according to claim 9, wherein the barrier metal layer comprises tungsten nitride.
11
Dependent← claim 9conducting metal layer
The method according to claim 9, wherein depositing the conductive metal layer comprises sputtering the conduc-tive metal layer over the barrier metal layer.
12
Dependent← claim 9Al
The method according to claim 9, wherein the con-ducting metal layer comprises aluminum.
13
Independentbarrier metal layerconducting metal layercap metal layerelectrode structure for GaN material device
A method of manufacturing an electrode structure for a device, comprising: forming an opening in an insulating layer to expose a semiconductor material surface region of a substrate through the opening; depositing a barrier metal layer over the insulating layer and onto the semiconductor material surface region of the substrate through the opening using atomic layer deposition; depositing a conducting metal layer over the barrier metal layer using sputtering; depositing a cap metal layer over the conducting metal layer using sputtering; and etching the cap metal layer, the conducting metal layer, and the barrier metal layer down to the insulating layer over an area.
14
Dependent← claim 13GaNbarrier metal layer
The method according to claim 13, wherein: the substrate comprises a gallium nitride material layer; forming the opening in the insulating layer comprises exposing a surface region of the gallium nitride mate-rial layer; and depositing the barrier metal layer comprises depositing the barrier metal layer onto the surface region of the gallium nitride material layer.
15
Dependent← claim 13Al
The method according to claim 13, wherein the conducting metal layer comprises aluminum.
16
Dependent← claim 13TiNWWN
The method according to claim 13, wherein the cap metal layer comprises at least one of titanium nitride, tungsten, and tungsten nitride. 11 12
17
Dependent← claim 13WN
The method according to claim 13, wherein the barrier metal layer comprises tungsten nitride.
18
Dependent← claim 13WNAlTiNW
The method according to claim 13, wherein: the barrier metal layer comprises tungsten nitride; the conducting metal layer comprises aluminum; and the cap metal layer comprises at least one of titanium nitride, tungsten, and tungsten nitride.
19
Dependent← claim 13barrier metal layer
The method according to claim 13, wherein depositing the barrier metal layer comprises depositing the barrier metal layer onto the insulating layer and onto the semicon-ductor material surface region of the substrate using atomic layer deposition. ∗ ∗ ∗ ∗ ∗
Device structures
Layer stacks claimed or described, ordered top of device to substrate.
electrode structure for GaN material device
TiNcap metal layer
Alconducting metal layer
WNbarrier metal layer
insulating layerinsulating layer
GaNsubstrate
Materials
Materials described outside the worked examples.
barrier metal layer
Barrier Metal Layer Deposited By ALD
conducting metal layer
Conducting Metal Layer In Electrode Stack
Process steps
Additional fabrication and treatment steps described in the patent.
1
Ald Deposition
Step 1
Process details
method:atomic layer deposition
deposited on:insulating layer and semiconductor material surface region through opening
Materials:WN
2
Reported properties
Performance values and ranges asserted in the specification or claims.
Property
Value
Material
Thickness
900–1025 Å
—
Thickness
Cited prior art
Patents and literature cited by this patent (applicant and examiner references).
Cited patents · 21
US 11,398,406 B211,398,406 B2 * 7/2022 Kuo.................. H01L 23/53238examiner
US 11,508,667 B111,508,667 B1 * 11/2022 Karp....................... H01L 23/50examiner
CN 111326574 ACN 111326574 A 6/2020
CN 114078815 ACN 114078815 A * 2/2022....... H01L 21/76802examiner
Why these are connected
Related documents with shared materials, methods, properties, or citations.
US 2008/0000678 A12008/0000678 A1 * 1/2008 Johnston................ C25D 5/022examiner
US 2008/0054472 A12008/0054472 A1 * 3/2008 Shinriki............ H01L 21/76843examiner
US 2014/0327140 A12014/0327140 A1 * 11/2014 Zhang............... H01L 21/28562examiner
US 2015/0108646 A12015/0108646 A1 * 4/2015 Chae................. H01L 21/76843examiner
US 2016/0013276 A12016/0013276 A1 1/2016 Morishita et al.
US 2016/0079404 A12016/0079404 A1 3/2016 Fujii et al.
US 2017/0358670 A12017/0358670 A1 12/2017 Kub et al.
US 2019/0378957 A12019/0378957 A1 * 12/2019 El-Ghoroury........... H01L 33/44examiner
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US 2021/0104433 A12021/0104433 A1 * 4/2021 Mukherjee............ C23C 16/045examiner
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US 2022/0037202 A12022/0037202 A1 * 2/2022 Lin................... H01L 21/76874examiner
US 2022/0050150 A12022/0050150 A1 * 2/2022 Chien..................... H01L 43/12examiner
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Cited non-patent literature · 2
European Search Report for Application No. 21191168.0 mailed Jan. 17, 2022.
Highly Conformal Thin Films of Tungsten Nitride Prepared by Atomic Layer Deposition From a Novel Precursor. Office Action for Taiwanese Application No. 110131204 mailed Sep. 7, 2022. Becker JS et al: “Highly Conformal Thin Films of Tungsten Nitride Prepared by Atomic Layer Deposition From a Novel Precursor”, Chemistry of Materials, American Chemical Society, US, vol. 15, No. 15, Jul. 20, 2003 (Jul. 20, 2003), pp. 2969-2976, XP008049005, ISSN: 0897-4756, DOI: 10.1021/CM021772S. Office Action from European Application No. 21191168.0 mailed Sep. 26, 2023.10.1021/CM021772S
US 2008/0000678 A12008/0000678 A1 * 1/2008 Johnston................ C25D 5/022examiner
US 2008/0054472 A12008/0054472 A1 * 3/2008 Shinriki............ H01L 21/76843examiner
US 2014/0327140 A12014/0327140 A1 * 11/2014 Zhang............... H01L 21/28562examiner
US 2015/0108646 A12015/0108646 A1 * 4/2015 Chae................. H01L 21/76843examiner
US 2016/0013276 A12016/0013276 A1 1/2016 Morishita et al.
US 2016/0079404 A12016/0079404 A1 3/2016 Fujii et al.
US 2017/0358670 A12017/0358670 A1 12/2017 Kub et al.
US 2019/0378957 A12019/0378957 A1 * 12/2019 El-Ghoroury........... H01L 33/44examiner
US 2020/0006132 A12020/0006132 A1 * 1/2020 Kuo.................. H01L 21/28562examiner
US 2021/0104433 A12021/0104433 A1 * 4/2021 Mukherjee............ C23C 16/045examiner
US 2021/0375776 A12021/0375776 A1 * 12/2021 Ho.................... H01L 21/76832examiner
US 2022/0037202 A12022/0037202 A1 * 2/2022 Lin................... H01L 21/76874examiner
US 2022/0050150 A12022/0050150 A1 * 2/2022 Chien..................... H01L 43/12examiner
US 2022/0216227 A12022/0216227 A1 * 7/2022 Rha................... H01L 27/11582examiner
TW 201314949 ATW 201314949 A 4/2013
WO 2013108844 A1WO 2013108844 A1 7/2013
Cited non-patent literature · 2
European Search Report for Application No. 21191168.0 mailed Jan. 17, 2022.
Highly Conformal Thin Films of Tungsten Nitride Prepared by Atomic Layer Deposition From a Novel Precursor. Office Action for Taiwanese Application No. 110131204 mailed Sep. 7, 2022. Becker JS et al: “Highly Conformal Thin Films of Tungsten Nitride Prepared by Atomic Layer Deposition From a Novel Precursor”, Chemistry of Materials, American Chemical Society, US, vol. 15, No. 15, Jul. 20, 2003 (Jul. 20, 2003), pp. 2969-2976, XP008049005, ISSN: 0897-4756, DOI: 10.1021/CM021772S. Office Action from European Application No. 21191168.0 mailed Sep. 26, 2023.10.1021/CM021772S
US 2008/0000678 A12008/0000678 A1 * 1/2008 Johnston................ C25D 5/022examiner
US 2008/0054472 A12008/0054472 A1 * 3/2008 Shinriki............ H01L 21/76843examiner
US 2014/0327140 A12014/0327140 A1 * 11/2014 Zhang............... H01L 21/28562examiner
US 2015/0108646 A12015/0108646 A1 * 4/2015 Chae................. H01L 21/76843examiner
US 2016/0013276 A12016/0013276 A1 1/2016 Morishita et al.
US 2016/0079404 A12016/0079404 A1 3/2016 Fujii et al.
US 2017/0358670 A12017/0358670 A1 12/2017 Kub et al.
US 2019/0378957 A12019/0378957 A1 * 12/2019 El-Ghoroury........... H01L 33/44examiner
US 2020/0006132 A12020/0006132 A1 * 1/2020 Kuo.................. H01L 21/28562examiner
US 2021/0104433 A12021/0104433 A1 * 4/2021 Mukherjee............ C23C 16/045examiner
US 2021/0375776 A12021/0375776 A1 * 12/2021 Ho.................... H01L 21/76832examiner
US 2022/0037202 A12022/0037202 A1 * 2/2022 Lin................... H01L 21/76874examiner
US 2022/0050150 A12022/0050150 A1 * 2/2022 Chien..................... H01L 43/12examiner
US 2022/0216227 A12022/0216227 A1 * 7/2022 Rha................... H01L 27/11582examiner
TW 201314949 ATW 201314949 A 4/2013
WO 2013108844 A1WO 2013108844 A1 7/2013
Cited non-patent literature · 2
European Search Report for Application No. 21191168.0 mailed Jan. 17, 2022.
Highly Conformal Thin Films of Tungsten Nitride Prepared by Atomic Layer Deposition From a Novel Precursor. Office Action for Taiwanese Application No. 110131204 mailed Sep. 7, 2022. Becker JS et al: “Highly Conformal Thin Films of Tungsten Nitride Prepared by Atomic Layer Deposition From a Novel Precursor”, Chemistry of Materials, American Chemical Society, US, vol. 15, No. 15, Jul. 20, 2003 (Jul. 20, 2003), pp. 2969-2976, XP008049005, ISSN: 0897-4756, DOI: 10.1021/CM021772S. Office Action from European Application No. 21191168.0 mailed Sep. 26, 2023.10.1021/CM021772S
US 2008/0000678 A12008/0000678 A1 * 1/2008 Johnston................ C25D 5/022examiner
US 2008/0054472 A12008/0054472 A1 * 3/2008 Shinriki............ H01L 21/76843examiner
US 2014/0327140 A12014/0327140 A1 * 11/2014 Zhang............... H01L 21/28562examiner
US 2015/0108646 A12015/0108646 A1 * 4/2015 Chae................. H01L 21/76843examiner
US 2016/0013276 A12016/0013276 A1 1/2016 Morishita et al.
US 2016/0079404 A12016/0079404 A1 3/2016 Fujii et al.
US 2017/0358670 A12017/0358670 A1 12/2017 Kub et al.
US 2019/0378957 A12019/0378957 A1 * 12/2019 El-Ghoroury........... H01L 33/44examiner
US 2020/0006132 A12020/0006132 A1 * 1/2020 Kuo.................. H01L 21/28562examiner
US 2021/0104433 A12021/0104433 A1 * 4/2021 Mukherjee............ C23C 16/045examiner
US 2021/0375776 A12021/0375776 A1 * 12/2021 Ho.................... H01L 21/76832examiner
US 2022/0037202 A12022/0037202 A1 * 2/2022 Lin................... H01L 21/76874examiner
US 2022/0050150 A12022/0050150 A1 * 2/2022 Chien..................... H01L 43/12examiner
US 2022/0216227 A12022/0216227 A1 * 7/2022 Rha................... H01L 27/11582examiner
TW 201314949 ATW 201314949 A 4/2013
WO 2013108844 A1WO 2013108844 A1 7/2013
Cited non-patent literature · 2
European Search Report for Application No. 21191168.0 mailed Jan. 17, 2022.
Highly Conformal Thin Films of Tungsten Nitride Prepared by Atomic Layer Deposition From a Novel Precursor. Office Action for Taiwanese Application No. 110131204 mailed Sep. 7, 2022. Becker JS et al: “Highly Conformal Thin Films of Tungsten Nitride Prepared by Atomic Layer Deposition From a Novel Precursor”, Chemistry of Materials, American Chemical Society, US, vol. 15, No. 15, Jul. 20, 2003 (Jul. 20, 2003), pp. 2969-2976, XP008049005, ISSN: 0897-4756, DOI: 10.1021/CM021772S. Office Action from European Application No. 21191168.0 mailed Sep. 26, 2023.10.1021/CM021772S